Scopion and Sub Zero
Scopion
At the main menu, hold White then press X, Up, L, R, Left, Right, X to unlock Scorpion in Single Player, Co-Op, and Versus modes
Sub Zero
At the main menu, hold White then press X, Down, Up, L(2), Up, X to unlock Sub-Zero in Single Player, Co-Op, and Versus modes.
More tricks, tips and cheats for this game are right here - Mortal Kombat: Shaolin Monks cheats
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