Red Silk adds Special Attack and Special Defense.
Fire Veil possibly protects the pokemon from dying in a fight. One time use per fight, I'm fairly sure.
Fire Dust raises Special Attack and Normal Attack
Fiery Gem keeps your pokemon at normal status (never poisoned, etc.) in sunneh weather
Fiery Globe makes water moves completely useless to fire types
And no, there's no fiery orb.
Hope this helps =D
ubr cuulness by Craizin the raizin. <3 FILIP R POLICE